What is pli?why is it used?

Programming Language Interface (PLI) of Verilog HDL is a mechanism to interface Verilog programs with programs written in C language. It also provides mechanism to access internal databases of the simulator from the C program.
PLI is used for implementing system calls which would have been hard to do otherwise (or impossible) using Verilog syntax. Or, in other words, you can take advantage of both the paradigms - parallel and hardware related features of Verilog and sequential flow of C - using PLI.